This PDF (mirror) contains loads of general information about performance tuning for Linux systems. It is neither new nor does it offer secret knowledge, but I have learned some little details by reading through it.
While searching for bottlenecks I found the sysstat package very useful. It logs system performance data from /proc that you can browse later using the accompanying command line tools or a GUI frontend named isag which draws nice graphs with GNUPlot.
Debian Packages:
If you want to tune the performance of an OpenLDAP server, these are some links you may like to check: